Reagents used in Froth Flotation processes


Tables I, II y III show the main

TABLE I. COLLECTORS.

Anionic.

Type

Chemical description

Minerals promoted

Xanthate

Sodium ethyl xanthate

Chalcocite, sphalerite, galena.

Xanthate

Sodium isopropyl xanthate

Most of sulphides

Xanthate

Potassium amyl xanthate

Most of sulphides

Thionocarbamate

Ethyl-isopropyl-thionocarbamate

Copper sulphides with pyrite

Dithiophosphate

Sodium diethyl dithiophosphate

Copper sulphides with gold and silver.

Mercaptans

Mercapthobenzothiazole

Pyrite in acid conditions.

Other Type

Fatty acid

Oleic acid, sodium oleate

Fluorite, Calcite, Cromite, Barite, Apatite

Alkyl sulphate

Sodium lauryl sulphate

Cromite, Fluorite, Barite.

Cationic.

Amine

Alkyl amine

Selective flotation sylvite-halite

Ammonium salts

Quaternary ammonium chloride

Quartz, Chalcopyrite, Silicates

TABLE II. FROTHERS.

Reagent.

Characteristic

Pine oil

Froth very stable and viscous.

Cresylic acid

Froth stable but little viscosity

MIBC

Very useful with fine particles

Polypropylene glycol

Froth with little consistence

Triethoxybutane

Froth is very fine

TABLE III. MODIFIERS.

Type

Agent

Action

pH Regulators.

CaO, Na2CO3, NaOH, HCl, H2SO4

pH

Activator.

CuSO4.5H2O

Sphalerite, pyrite

Activator.

Pb +2, like nitrate or acetate

Stibnite

Activator.

SH- or S= , like NaHS, Na2S

oxidized sulphides, carbonates

Depressant

Zn+2, like Zn SO4.

Sphalerite, pyrite

Depressant

CN- , like NaCN or Ca(CN)2

Sphalerite, pyrite

Depressant

SO2

Sphalerite, pyrite,

Depressant

Quebracho

Calcite.